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TY - JOUR
TI - Micropollutants in Urban Runoff from Traffic Areas: Target and Non-Target Screening on Four Contrasted Sites
AU - Gasperi, Johnny
AU - Le Roux, Julien
AU - Deshayes, Steven
AU - Ayrault, Sophie
AU - Bordier, Louise
AU - Boudahmane, Lila
AU - Budzinski, Hélène
AU - Caupos, Emilie
AU - Caubrière, Nadège
AU - Flanagan, Kelsey
AU - Guillon, Martin
AU - Huynh, Nina
AU - Labadie, Pierre
AU - Meffray, Laurent
AU - Neveu, Pascale
AU - Partibane, Chandirane
AU - Paupardin, Julien
AU - Saad, Mohamed
AU - Varnede, Lucie
AU - Gromaire, Marie-Christine
T2 - Water
AB - Although runoff from trafficked urban areas is recognized as a potentially significant pathway of micropollutants, runoff pollution remains poorly documented, except for relatively few historical pollutants such as some metals and hydrocarbons. Therefore, in this work, road and parking lot runoff from four sites with contrasting traffic levels were analyzed for a very broad spectrum of molecules and elements. A total of 128 pollutants and micropollutants were monitored, including inorganic (n = 41) and organic (n = 87) pollutants. Both the dissolved and particulate phases were considered. For a reduced number of samples, non-targeted screening by high-resolution mass spectrometry (HRMS) was carried out. For targeted screening, the contamination profiles were quite homogeneous, but the concentrations significantly differed between the different sites. Sites with the highest traffic density exhibited the highest concentrations for polycyclic aromatic hydrocarbons (PAHs), some traffic-related metals, alkylphenols and phthalates. Overall, for most micropollutants, the parking lot runoff exhibited the lowest concentrations, and the specificity of this site was confirmed by its HRMS fingerprint. Non-target screening allowed the sites to be discriminated based on the occurrence of specific compounds. Unlike the results of targeted screening, the HRMS intra-site variability was lower than its inter-site variability. Unknown substances were tentatively identified, either characteristic of each site or ubiquitous of all samples.
DA - 2022/01//
PY - 2022
DO - 10.3390/w14030394
DP - www.mdpi.com
VL - 14
IS - 3
SP - 394
LA - en
PB - Multidisciplinary Digital Publishing Institute
ST - Micropollutants in Urban Runoff from Traffic Areas
UR - https://www.mdpi.com/2073-4441/14/3/394
Y2 - 2022/01/31/08:22:32
KW - micropollutants
KW - non-target screening
KW - road runoff
KW - stormwater
KW - target screening
ER -