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TY - JOUR
TI - Smectic liquid-crystalline order in suspensions of highly polydisperse goethite nanorods
AU - Vroege, G.J.
AU - Thies-Weesie, D.M.E.
AU - Petukhov, A.V.
AU - Lemaire, B.J.
AU - Davidson, P.
T2 - Advanced Materials
AB - Optical Bragg reflections and small-angle X-ray scattering (see figure) reveal that dispersions of Goethite (FeOOH) nanorods spontaneously form layered (smectic A) structures, although their 55% length polydispersity exceeds the theoretical limit by a factor of three. Here, sedimentation and size partitioning contribute to a very rich phase behavior including nematic and columnar phases. This suggests the application of the self-organizing tendencies of such mineral liquid crystals to obtain materials with very diverse nanostructures.
DA - 2006///
PY - 2006
VL - 18
IS - 19
SP - 2565
EP - 2568
SN - 0935-9648
ER -